Issue 0, 1985

Heterocycles by cycloaddition. Part 7. Cycloaddition reactions of mesoionic dithiolones with fulvenes

Abstract

The reactions of fulvenes with several mesoionic compounds have been investigated. The mesoionic dithiolones (7) gave regio- and stereo-selective [4π+ 2π] cycloadducts (11)–(13) across the endocyclic double bonds of fulvenes, but no periselectivity was observed with unsymmetrical fulvenes. Several other mesoionic ring systems failed to react or gave complex reaction products.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1985, 1245-1247

Heterocycles by cycloaddition. Part 7. Cycloaddition reactions of mesoionic dithiolones with fulvenes

H. Kato, N. Aoki, Y. Kawamura and K. Yoshino, J. Chem. Soc., Perkin Trans. 1, 1985, 1245 DOI: 10.1039/P19850001245

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