SCHEDULED MAINTENANCE
Anilines, 3-substituted with an ortho-para activating group, undergo, after protection of the amino group by acetylation, electrophilic addition with platinum(II)-co-ordinated 1,1-dimethylallene. This alkenylation is regiospecific, affording o-isopentenyl derivatives. A similar reaction is also observed with diphenylamine. A catalytic process is described.
A. De Renzi, A. Panunzi, A. Saporito and A. Vitagliano, J. Chem. Soc., Perkin Trans. 1, 1985, 1095 DOI: 10.1039/P19850001095
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