An efficient four-step sequence to 19-epiajmalicine, a rare heteroyohimbane alkaloid, which requires mild conditions and utilises ajmalicine as an easily accessible starting material, is described.
G. Palmisano, B. Danieli, G. Lesma and R. Riva, J. Chem. Soc., Perkin Trans. 1, 1985, 923 DOI: 10.1039/P19850000923
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