SCHEDULED MAINTENANCE
The preparation of the αβ-unsaturated acylsilane (1) and some β-functionalised acylsilanes (2)–(5) is described. On irradiation, the β-azidoacylsilane (2) was converted into the enol form (19) of a β-methyliminoacylsilane, and the β-isothiocyanatoacylsilane (4) underwent isomerisation into the thioamide (23; R = SiMe3).
D. I. Gasking and G. H. Whitham, J. Chem. Soc., Perkin Trans. 1, 1985, 409 DOI: 10.1039/P19850000409
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