A study has been made of the different contributions to the entropy of adsorption in Henry's zone of several hydrocarbons on Aerosil with different degrees of hydrophobicity. The statistical-mechanical interpretation of the experiments on the adsorption of isobutene on hydroxylated Aerosil shows that there is mobile adsorption with loss of one rotational degree of freedom.
J. Cortés, G. Troncoso, L. Alzamora and E. Valencia, J. Chem. Soc., Faraday Trans. 1, 1985, 81, 1631 DOI: 10.1039/F19858101631
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