SCHEDULED MAINTENANCE
The solvent properties of the ZnCl2+ H2O system towards Co2+ differ from those of other metal chloride aqueous systems. In CaCl2·xH2O, for example, tetrahedral chlorocobaltate(II) species are increasingly generated with decreasing water content for x= 12, but not in ZnCl2·xH2O, where octahedral coordination of Co2+ is preserved even for x= 3.
J. A. Duffy and G. L. Wood, J. Chem. Soc., Faraday Trans. 1, 1985, 81, 265 DOI: 10.1039/F19858100265
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