Results of a spectrophotometric study at different temperatures of the monomer⇌dimer equilibrium of thionine solutions in H2O and in D2O confirm and extend previous findings, obtained by studying the self-association of Methylene Blue in aqueous solutions, concerning the involvement of solvent rearrangement processes in the stacking of planar dye molecules.
S. L. Fornili, G. Sgroi, L. Palumbo and V. Izzo, J. Chem. Soc., Faraday Trans. 1, 1985, 81, 255 DOI: 10.1039/F19858100255
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