Stannane or the methylstannanes SnMe4–nHn(n= 1–4) react in fluorosulphuric acid at low temperature (–90°C) to produce SnMe3–nHn+(n= O–3) and 1H, 13C, and 119Sn n.m.r. spectroscopy have been used in their characterisation. Hydrogen-evolution, 119Sn n.m.r., and Mossbauer evidence is presented to show that at higher temperatures these species decompose to Sn2+, Sn2+ plus SnMe22+ and SnMe22+ depending on the starting hydride.
T. Birchall and V. Manivannan, J. Chem. Soc., Dalton Trans., 1985, 2671 DOI: 10.1039/DT9850002671
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...