The kinetics of reduction of two nickel (IV)–oxime complexes by the organic radicals H2ĊOH, (CH3)HĊOH, (CH3)2ĊOH, ĊO2–, and (CH3)2ĊO– have been examined in aqueous solution using the pulse radiolysis technique. Difference spectra indicate that the electron is transferred to the metal centre and spectroscopic characterization of the nickel(III) transients is presented.
S. Baral and A. G. Lappin, J. Chem. Soc., Dalton Trans., 1985, 2213 DOI: 10.1039/DT9850002213
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