Issue 9, 1985

The peroxodisulphate–hexacyanoferrate(II) reaction. Reactivity and ionic association in isodielectric water–co-solvent mixtures

Abstract

The association constants of the potassium peroxodisulphate ion pair (KS2O8) and the potassium hexacyanoferrate(II) ion pair [KFe(CN)63–] and the rate constant between peroxodisulphate and hexacyanoferrate(II) ions have been measured in several water–co-solvent mixtures. The assumption of ionic association does not provide a satisfactory interpretation of the experimental results.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1985, 1975-1976

The peroxodisulphate–hexacyanoferrate(II) reaction. Reactivity and ionic association in isodielectric water–co-solvent mixtures

J. Baños, F. Sánchez-Burgos and M. C. Carmona-Guzmán, J. Chem. Soc., Dalton Trans., 1985, 1975 DOI: 10.1039/DT9850001975

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