The complexes trans-[MX(NO)L4]2+[M = Ru or Fe, X = Cl or Br, L = pyridine or o-phenylenebis(dimethylarsine)] react with hydroxylamine to afford the corresponding one-electron reduced species. The reaction appears to be the first to produce a (M–NO)2+ group.
K. Aoyagi, M. Mukaida, H. Kakihana and K. Shimizu, J. Chem. Soc., Dalton Trans., 1985, 1733 DOI: 10.1039/DT9850001733
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