Issue 3, 1985
From the journal:

Journal of the Chemical Society, Dalton Transactions

Trimethylphosphine polyhydrides of tungsten and rhenium

David Lyons  and  Geoffrey Wilkinson  

Abstract

The new compounds WH6(PMe3)3, ReH7(PMe3)2, ReH7(PMe3)2·PhNH2, and Re2H8(PMe3)4 have been synthesised. Improved syntheses of MH4(PMe3)4(M = MO or W) are also described. The complex WH6(PMe3)3 reacts with carbon dioxide under pressure to yield the fluxional molecule [graphic omitted])(O2CH)(PMe3)3 with uni- and bi-dentate formate groups. The compounds have been characterised by infrared and nuclear magnetic resonance (1H and 31P) spectroscopy.

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Article information

DOI
https://doi.org/10.1039/DT9850000587
Article type
Paper

J. Chem. Soc., Dalton Trans., 1985, 587-590

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Trimethylphosphine polyhydrides of tungsten and rhenium

D. Lyons and G. Wilkinson, J. Chem. Soc., Dalton Trans., 1985, 587 DOI: 10.1039/DT9850000587

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