Photolysis of the 8-oxa-3,4-diazatricyclo[5.1.0.02,6]oct-4-enes (7) results in a ring transformation to give the 6-formyl-2,3-diazabicyclo[3.1.0]hex-3-enes (9), whereas the 8-aza compounds (8) give the 2-amino-3-cyano-5-azabicyclo[2.1.0]pentanes (12) by cleavage of the N–N bond.
J. Kurita, H. Sakai and T. Tsuchiya, J. Chem. Soc., Chem. Commun., 1985, 1769 DOI: 10.1039/C39850001769
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