Issue 24, 1985
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis and X-ray crystal structure of the cluster compound [Rh12H2(µ3-CO)3(µ-CO)9(CO)13] containing a metallic array formed by three superimposed cofacial octahedral units

Gianfranco Ciani,   Angelo Sironi  and  Secondo Martinengo  

Abstract

The neutral species [Rh12H2(CO)25], obtained by reaction of [Rh14(CO)25]4– with CF3CO2H in the presence of CO and Chloride ions, contains a new Rh12 metallic array formed by superimposition of three face-sharing octahedral units, and in donor solvents readily gives the [Rh12H(CO)25]– monoanion.

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Article information

DOI
https://doi.org/10.1039/C39850001757
Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 1757-1759

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Synthesis and X-ray crystal structure of the cluster compound [Rh12H2(µ3-CO)3(µ-CO)9(CO)13] containing a metallic array formed by three superimposed cofacial octahedral units

G. Ciani, A. Sironi and S. Martinengo, J. Chem. Soc., Chem. Commun., 1985, 1757 DOI: 10.1039/C39850001757

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