Desilylation by fluoride anion of benzyldimethyl(trimethylsilylmethyl)ammonium halides having a Cl–, CN–, or AcO– substituent on the benzene ring gave high yields of the Sommelet–Hauser rearrangement products at room temperature.
M. Nakano and Y. Sato, J. Chem. Soc., Chem. Commun., 1985, 1684 DOI: 10.1039/C39850001684
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