The Brønsted relationship for the leaving hydroxy group in the phosphorylatin of alkaline phosphatase has a β value of –0.19; by comparison with βeq. for the overall equilibrium (–1.35) there is little change in the charge on the leaving oxygen atom between the ground- and transition-states.
A. D. Hall and A. Williams, J. Chem. Soc., Chem. Commun., 1985, 1680 DOI: 10.1039/C39850001680
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