Issue 23, 1985

Alkali cation transport by proton-ionizable macrocycles in a H2O–CH2Cl2–H2O bulk liquid membrane system

Abstract

Coupled H+–M+(M = Na, K, Rb, or Cs) transport of individual M+ and binary M+ mixtures in which K+ is transported selectively in a 1 M MOH–CH2Cl2–HNO3/H2O (pH 1.5 and ∼6) bulk liquid membrane system has been accomplished using a proton-ionizable 4-pyridone-fused-18-crown-6 macrocycle with an attached C8H17 chain (2).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 1676-1677

Alkali cation transport by proton-ionizable macrocycles in a H2O–CH2Cl2–H2O bulk liquid membrane system

R. M. Izatt, G. C. Lindh, G. A. Clark, J. S. Bradshaw, Y. Nakatsuji, J. D. Lamb and J. J. Christensen, J. Chem. Soc., Chem. Commun., 1985, 1676 DOI: 10.1039/C39850001676

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