The reaction of symmetrical sulphites with t-butylmagnesium chloride in the presence of chiral aminoalcohols has been found to proceed in an asymmetric way affording chiral t-butylsulphinates in 40–70% enantiomeric excess.
J. Drabowicz, S. Legedź and M. Mikołajczyk, J. Chem. Soc., Chem. Commun., 1985, 1670 DOI: 10.1039/C39850001670
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