The synthesis of ester(6b) and lactone (7a)via reductive photocyclisation, kinetically controlled alkylation and acylation, and reductive cleavage of γ-lactone illustrates a new general method for the preparation of the ipecac and heteroyohimbine alkaloids.
T. Naito, N. Kojima, O. Miyata and I. Ninomiya, J. Chem. Soc., Chem. Commun., 1985, 1611 DOI: 10.1039/C39850001611
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