Reaction of the funcationalised macrocycle (1a) with copper (II) ions in solution leads to the assembly of a trinuclear bis(macrocyclic) complex which has been studied by X-ray crystallography and cyclic voltammetry; the complex contains a linear trinuclear array of copper atoms in which the central copper is in a square-planer environment.
G. Ferguson, C. R. Langrick, D. Parker and K. Matthes, J. Chem. Soc., Chem. Commun., 1985, 1609 DOI: 10.1039/C39850001609
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