Phenyl(arylsuphonyl)acetylenes add thermally or photochemically to alkenes to afford stereospecifically trans products which are formal adducts of the two fragments derived from homolytic cleavage of the carbon–sulphur bond.
O. De Lucchi, G. Licini, L. Pasquato and M. Senta, J. Chem. Soc., Chem. Commun., 1985, 1597 DOI: 10.1039/C39850001597
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