The formation of 3-arylbenzaldehydes through rearrangement of 3-aryl-8-oxabicyclo[3.2.1]oct-2-en-7-ones is reported, together with various rearrangement reactions of 2-aryl-8-oxabicyclo[3.2.]oct-6-en-3-ones, and a novel approach to the natural product acamelin.
J. Mann, P. D. Wilde and M. W. Finch, J. Chem. Soc., Chem. Commun., 1985, 1543 DOI: 10.1039/C39850001543
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