Synthesis and reactivity of a novel unsaturated dimanganese hydride complex, [Mn2H2(CO)6{(OEt)2POP(OEt)2}]. X-Ray Structure of [Mn4Cu2H6(CO)12{(OEt)2-POP(OEt)2}2]
Abstract
The synthesis of [Mn2H2(CO)6{(OEt)2POP(OEt)2}] and its reactions with tetrahydrothiophene, methyl-triphenylphosphinegold(I), sodium amalgam followed by triphenylphosphine–group 1b metal cations, and with copper(I) haliders are described; the structure of [Mn4Cu2H6(CO)12{(OEt)2-POP(OEt)2}2] has been established by X-ray diffraction.
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