Issue 21, 1985
From the journal:

Journal of the Chemical Society, Chemical Communications

[Hg3(SCH2CH2S)4]2– and {[Hg2(SCH2CH2S)3]2–}n: examples of trinuclear and quasi-isolated binuclear polymeric mercury thiolate anions

Gerald Henkel,   Peter Betz  and  Bernt Krebs  

Abstract

On varying the reaction conditions, of HgCl2 with ethane-1,2-dithiolate and Ph4PBr in methanol yields either [Ph4P]2[Hg3(SCH2CH2S)4] containing isolated trinuclear anions or [Ph4P]2[Hg2(SCH2CH2S)3] with polymeric anions composed of quasi-isolated binuclear subunits; both mercury thiolates may reflect characteristic structural features of biologically active species.

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Article information

DOI
https://doi.org/10.1039/C39850001498
Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 1498-1499

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[Hg3(SCH2CH2S)4]2– and {[Hg2(SCH2CH2S)3]2–}n: examples of trinuclear and quasi-isolated binuclear polymeric mercury thiolate anions

G. Henkel, P. Betz and B. Krebs, J. Chem. Soc., Chem. Commun., 1985, 1498 DOI: 10.1039/C39850001498

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