Both diastereoisomer of ButP(O)(Cl)NHR [RNH =(S)-PhMeCHNH] give the same mixture (55/45) of the diastereoisomers of ButP(O)(NNBut)NHR on reaction with ButNH2 in dilute MeCN solution, but some stereospecificity is seen at higher amine concentrations.
S. Freeman and M. J. P. Harger, J. Chem. Soc., Chem. Commun., 1985, 1394 DOI: 10.1039/C39850001394
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