Solution photolysis of (η-C5H5)Rh(C2H4)2 leads to substitution of ethane in the presence of donor ligands and to oxidative addition with R3SiH (R = Me or Et); photolysis in inert matrices causes reversible loss of ethane, but in reactive matrices substitution by N2 and CO takes place.
D. M. Haddleton and R. N. Perutz, J. Chem. Soc., Chem. Commun., 1985, 1372 DOI: 10.1039/C39850001372
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