Rapid oxidative metal insertion into a macrocylic ring from a ‘metal-out’ position and identification of a stable ‘metal-in’ isomer of a NiII–cyclamtetra-acetate complex

Eiichi Kimura; Tohru Koike; Mayumi Yamaoka; Mutsuo Kodama

doi:10.1039/C39850001341

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Rapid oxidative metal insertion into a macrocylic ring from a ‘metal-out’ position and identification of a stable ‘metal-in’ isomer of a Ni^II–cyclamtetra-acetate complex

Eiichi Kimura, Tohru Koike, Mayumi Yamaoka and Mutsuo Kodama

Abstract

The previously unknown ‘Ni^II-in’ complex of cyclamtetra-acetate has been prepared from the ‘Ni^II-out’ isomer by oxidative intramolecular (out → in) translocation of Ni and subsequent reduction to Ni^II.

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DOI: https://doi.org/10.1039/C39850001341
Article type: Paper

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J. Chem. Soc., Chem. Commun., 1985, 1341-1343

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Rapid oxidative metal insertion into a macrocylic ring from a ‘metal-out’ position and identification of a stable ‘metal-in’ isomer of a Ni^II–cyclamtetra-acetate complex

E. Kimura, T. Koike, M. Yamaoka and M. Kodama, J. Chem. Soc., Chem. Commun., 1985, 1341 DOI: 10.1039/C39850001341

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Journal of the Chemical Society, Chemical Communications

Rapid oxidative metal insertion into a macrocylic ring from a ‘metal-out’ position and identification of a stable ‘metal-in’ isomer of a Ni^II–cyclamtetra-acetate complex

Abstract

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Rapid oxidative metal insertion into a macrocylic ring from a ‘metal-out’ position and identification of a stable ‘metal-in’ isomer of a Ni^II–cyclamtetra-acetate complex

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