Photochemical reactions between [Mn2(CO)8(PR3)]2](R = Et, Bun, OEt) and alkyl halides (R′X) proceed to completion in 2 to 4 h yielding equimolar quantities of [MnR′(CO)4PR3] and [MnX(CO)4PR3], by a route involving reaction of R′X with mononuclear intermediates.
M. A. Biddulph, R. Davis, C. H. J. Wells and F. I. C. Wilson, J. Chem. Soc., Chem. Commun., 1985, 1287 DOI: 10.1039/C39850001287
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