The Pummerer reaction of 1,5-dithiacyclo-octane 1-oxide with acetic anhydride afforded the α-acetylated cyclo-octane via the intermediate formation of the disulphide dication.
N. Furukawa, A. Kawada, T. Kawai and H. Fujihara, J. Chem. Soc., Chem. Commun., 1985, 1266 DOI: 10.1039/C39850001266
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