Radical anions were generated by reduction of aliphatic diazenes with sodium–potassium alloy combined with u.v. irradiation (primary alkyl azo compounds), sodium–potassium alloy (secondary and tertiary alkyl azo compounds) and with crotylpotassium combined with u.v. irradiation (primary, secondary, and tertiaryl alkyl azo compounds); nitrogen hyperfine coupling constants range from 0.775 to 0.883 mT.
R. Sustmann and R. Sauer, J. Chem. Soc., Chem. Commun., 1985, 1248 DOI: 10.1039/C39850001248
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...