The addition of Ir to Rh/SiO2 and Rh-Ti/SiO2 CO hydrogenation catalysts substantially suppresses methanation and enhances C2-oxygenate formation; consequently high selectivities for C2-oxygenates such as MeCHO and EtOH are achieved.
T. Fukushima, M. Ichikawa, S. Matsushita, K. Tanaka and T. Saito, J. Chem. Soc., Chem. Commun., 1985, 1209 DOI: 10.1039/C39850001209
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