Both 1-amino-1,2,3-azadiboriridine and bi(1,2,3-azadiboriridin-1-yl) are found by ab initio molecular orbital calculations to prefer conformations with coplanar lone-pair orbital axes on the adjacent nitrogen atoms; the latter molecule is predicted to prefer a fully coplanar (D2h) conformation.
N. V. Riggs and L. Radom, J. Chem. Soc., Chem. Commun., 1985, 1193 DOI: 10.1039/C39850001193
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