Quadridentate bis-imine nickel(II) complexes have been formed from 7-formylindoles and 1,2-diamnobenzene: an X-ray crystal structure determination of the chloroform solvate of the N,N′-bis(4,6-dimethoxyindol-7-ylidene)-1,2-diaminobenzene complex shows severe distortion from planarity and a distance of 2.96 Å between the C-2 indole atoms.
D. S. C. Black, D. C. Craig, N. Kumar and L. C. H. Wong, J. Chem. Soc., Chem. Commun., 1985, 1172 DOI: 10.1039/C39850001172
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