Photochemical reaction of the trans-fused bicyclic ketone (1) in solution gave the unsaturated aldehyde (4), whereas irradiation of the cis-fused isomer (2) in methanol led to inefficient photoreduction.
R. J. Batten and H. A. J. Carless, J. Chem. Soc., Chem. Commun., 1985, 1146 DOI: 10.1039/C39850001146
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