Ab initio and semi-empirical MNDO calculations indicate that monomeric dilithiated and bis-magnesyl derivatives of carboxylic acids (Ivanoff reagents) favour the 1,3-1,3′ doubly bridged structures generally found in metallated Y-conjugated dianion systems.
J. Kaneti, P. von Ragué Schleyer and A. J. Kos, J. Chem. Soc., Chem. Commun., 1985, 1014 DOI: 10.1039/C39850001014
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