Issue 15, 1985
From the journal:

Journal of the Chemical Society, Chemical Communications

Rearrangement of chloromethylphosphinidene into methylenechlorophosphine in the co-ordination sphere of tungsten. Stabilization of an unhindered P[double bond, length half m-dash]C double bond without deactivation by π-complexation

Bernard Deschamps  and  François Mathey  

Abstract

Transient [ClCH2-P[double bond, length half m-dash]W(CO)5] rearranges into stable (η2-CH2[double bond, length half m-dash]-PCl)W(CO)5 which can be characterized in solution by i.r., 1H n.m.r., and 31P n.m.r. spectroscopy and reacts readily with alcohols and conjugated dienes as a σ-P-co-ordinated species.

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Article information

DOI
https://doi.org/10.1039/C39850001010
Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 1010-1012

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Rearrangement of chloromethylphosphinidene into methylenechlorophosphine in the co-ordination sphere of tungsten. Stabilization of an unhindered P[double bond, length half m-dash]C double bond without deactivation by π-complexation

B. Deschamps and F. Mathey, J. Chem. Soc., Chem. Commun., 1985, 1010 DOI: 10.1039/C39850001010

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