Reaction of B10H14 with Et3PAuMe affords the triple cluster [(H12B10Au)(AuPEt3)4(AuB10H12)], and with Cy3PAuMe (CY = cyclohexyl) the substituted complex [Cy3PAu(B10H13)] is isolated; a mechanism for the formation of the triple cluster is proposed.
A. J. Wynd, S. E. Robins, D. A. Welch and A. J. Welch, J. Chem. Soc., Chem. Commun., 1985, 819 DOI: 10.1039/C39850000819
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