Issue 12, 1985

Carbon–carbon bond formation between α-halogenoketones and aldehydes promoted by cerium(III) iodide or cerium(III) chloride–sodium iodide

Abstract

α-Halogenoketones react with aldehydes to form α,β-unsaturated ketones accompanied by dehalogenation in the presence of cerium(III) iodide, but use of cerium(III) chloride–sodium iodide results in the formation of β-keto alcohols.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 777-778

Carbon–carbon bond formation between α-halogenoketones and aldehydes promoted by cerium(III) iodide or cerium(III) chloride–sodium iodide

S. Fukuzawa, T. Fujinami and S. Sakai, J. Chem. Soc., Chem. Commun., 1985, 777 DOI: 10.1039/C39850000777

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