Issue 12, 1985

η-Arene and η-cyclohexadiene tungsten chemistry: new synthetic routes to tertiary phosphine–hydride derivatives

Abstract

Convenient syntheses of W(η-C6H8)(PMe3)3H2 and W(η-C6H6)(PMe3)2H2 are described; these compounds, together with W(η-C6H6)(η-C6H8)H2, W(η-PhMe)(PMe3)2H2, W(η-PhMe)(Me2PCH2CH2PMe2)H2, and W(η-C6H6)(PMe3)3 have been synthesized using either tungsten atoms or by the reductive labilization of η-PhMe ring of W(η-PhMe)2 using potassium metal.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 771-773

η-Arene and η-cyclohexadiene tungsten chemistry: new synthetic routes to tertiary phosphine–hydride derivatives

M. L. H. Green and G. Parkin, J. Chem. Soc., Chem. Commun., 1985, 771 DOI: 10.1039/C39850000771

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