Interactive molecular graphics is demonstrated to be a simple yet powerful means of probing semi-quantitatively steric effects in organometallic compounds such as the iron butterfly clusters Fe4(CO)12CR in which such effects are found to restrict both the orientation and the nature of the carbido substituent, R.
J. M. Newsam and J. S. Bradley, J. Chem. Soc., Chem. Commun., 1985, 759 DOI: 10.1039/C39850000759
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