Issue 11, 1985

Tellurocarbohydrates

Abstract

The 1-Te-(2,3,4,6-tetra-O-acetyl-β-D-glucosyl) phosphorotelluroate (3) obtained by reaction of α-acetobromoglucose (1) with the triethylamnonium phosphorotelluroate (2) gives on treatment with methanol bis(β-D-glucosyl) ditelluride (6) which on reduction with NaBH4 is converted into sodium 1-telluro-β-D-glucoside (7), which was not isolated but in the presence of n-propyl bromide was alkylated in situ to give n-propyl 1-telluro-β-D-glucoside (8); compounds (3), (6), and (8) are the first representatives of their class.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 693-694

Tellurocarbohydrates

J. Czyżewska-Chlebny and M. Michalska, J. Chem. Soc., Chem. Commun., 1985, 693 DOI: 10.1039/C39850000693

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