The pro-R hydrogen of (+)-N,N-dimethylamphetamine chromium tricarbonyl can be stereospecifically substituted via sequential treatment with BunLi and an electrophile, with rotation of configuration to give for example N-methylpseudoephedrine after decomplexation.
J. Blagg and S. G. Davies, J. Chem. Soc., Chem. Commun., 1985, 653 DOI: 10.1039/C39850000653
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