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The crystal structure of the free base meso tetra(2,4,6-trimethoxyphenyl)porphyrin indicates that the bulky meso substituents form ‘pockets’ on both faces of the porphyrin plane 2.27 Å deep and 9.74 Å on the diagonal between o-methoxy oxygen atoms on the same face.
K. W. Gold, D. J. Hodgson, A. Gold, J. E. Savrin and G. E. Toney, J. Chem. Soc., Chem. Commun., 1985, 563 DOI: 10.1039/C39850000563
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