Treatment of TaClH2(PMe3)4 with CO or oxidation of [Ta(CO)6]– with TaCl5 in diethyl ether–PMe3 solutions provides TaCl(CO)3(PMe3)3, a capped trigonal prismatic complex whose structure has been determined by X-ray diffraction; bromo and iodo analogues have been isolated by oxidation of [Ta(CO)6]– with Br2 or I2 in diethyl ether–PMe3 solutions.
M. L. Luetkens, D. J. Santure, J. C. Huffman and A. P. Sattelberger, J. Chem. Soc., Chem. Commun., 1985, 552 DOI: 10.1039/C39850000552
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