Examples of mild, additive Pummerer rearrangements are given; one example involves asymmetric carbon–carbon bond formation as the key step for synthesis of (–)-methyl jasmonate.
G. H. Posner, E. Asirvatham and S. F. Ali, J. Chem. Soc., Chem. Commun., 1985, 542 DOI: 10.1039/C39850000542
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