3-Acetonyl-4-methyl-1,3-thiazolium chloride is resistant to basic hydrolysis to its free-thiol form and undergoes instead a unique intramolecular cyclization to yield a stable bicyclic form.
M. B. Doughty and D. S. Lawrence, J. Chem. Soc., Chem. Commun., 1985, 454 DOI: 10.1039/C39850000454
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