Osmium tetroxide-catalysed cis-hydroxylation of 5-vinyl-4,5-dihydroisoxazoles proceeds stereoselectively affording the anti-products in fair to excellent diastereoisomeric excess; an entry to optically active compounds is also described.
R. Annunziata, M. Cinquini, F. Cozzi and L. Raimondi, J. Chem. Soc., Chem. Commun., 1985, 403 DOI: 10.1039/C39850000403
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