A cluster compound with an unsupported, dative metal–metal bond: structure and unusual nonrigidity of (Me3P)(OC)4OsOs3(CO)11
Abstract
The cluster compound (Me3P)(OC)4OsOs3(CO)11, which contains an unbridged Os–Os donor–acceptor bond, exhibits stereochemical nonrigidity in solution that involves all the carbonyl ligands.
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