Diphenylphosphinated ethylene oligomers can used as homogeneous polymeric reagents at 90 °C in carbon tetrachloride to form alkyl chlorides from alcohols and since these functionalized ethylene oligomers precipitate quantitatively from solution at 25 °C, they can be easily recovered and separated from the reaction products and can be partially recycled.
D. E. Bergbreiter and J. R. Blanton, J. Chem. Soc., Chem. Commun., 1985, 337 DOI: 10.1039/C39850000337
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