Reaction of (η2-ethene)bis(triphenylphosphine)platinum(0) with bis(trimethylsilyl)sulphurdiimide yields cis-[Pt(NSNSiMe3)2(PPh3)2]the first example of a complex containing the RNSN– ligand, in this case sigma bonded to platinum via nitrogen.
N. P. C. Walker, M. B. Hursthouse, C. P. Warrens and J. D. Woollins, J. Chem. Soc., Chem. Commun., 1985, 227 DOI: 10.1039/C39850000227
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